1.
Chem Commun (Camb)
; 56(31): 4328-4331, 2020 Apr 21.
Artículo
en Inglés
| MEDLINE
| ID: mdl-32191244
RESUMEN
Vapour-phase surface-initiated cationic polymerisation of ethylvinylether occurs at single-crystals of the σ-alkane complex [Rh(Cy2PCH2CH2PCy2)(NBA)][BArF4]. This new surface interface makes these normally very air sensitive materials tolerant to air, while also allowing for onward single-crystal to single-crystal reactivity at metal sites within the lattice.